If you haven't heard the term "Win More" before, generally speaking it's a bonus which triggers when you're already winning that allows you to win more. These mechanics typically fall into the category of "noob traps" because they often look flashy and cool on paper but in practice they provide no meaningful benefit. If you're already winning, winning more is pointless. For more details, you can check U4GM.
The support gem Cast on Melee Kill is a good example of a win more mechanic. In order to trigger the linked spell reliably, your melee skill needs to be able to kill monsters quickly and reliably. But if your melee skill is already clearing reliably then what do you need the triggered spell for? Cast on Melee Kill is a really egregious example of a win more mechanic which is why it's never used. It also doesn't help that the melee and spell aspects of the gem destructively interfere with each other.
It's just a matter of building around a mechanic to make it meaningful without the first "win more" condition you are setting. Yes, by themselves each of the examples is a "win more" if you only use it as how the base mechanic is defined, but when combo'd with uniques/gems/skills and different play styles, they can be become the core of a build rather than something on top of another build. The sky really is the limit for Path Of Exile and we can only see it getting bigger. As we said it is very easy to get into and we can even offer you the best place to buy POE currency trade if you want to get even more into the game.
You're falling into the trap of the paper benefits win more mechanics claim to give versus the actual gameplay benefits they provide. Take your shock example, the difference between 6 hits and 9 hits is taking what is a already a clearly trivial fight and making it even more trivial by shortening it by about 1-2 seconds. If 2 seconds is the difference between life and death for your build then you'll find a lot more benefit from boosting your defenses than trying to scale a win more mechanic.
For shock to meaningfully impact on a fight, you need to be dealing about 10% of the enemy's base life in damage per hit. I think if you take a quick look around at what builds rely on shock to scale their damage there are none. Contrast that with the old shock which was not a win more mechanic and many builds relied on it to scale damage. Sure there are options like lightning trap but these give guaranteed shock values which is a completely different mechanic.
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